Aminophosphonic and Aminophosphinic Acids: Chemistry and by Valery P. Kukhar, Harry R. Hudson

By Valery P. Kukhar, Harry R. Hudson

Aminophosphinic and aminoposphonic acids, man made analogs to average amino acids, have attained a place of prominence in research--particularly in learn regarding the amendment of physiological methods in residing organisms.

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L. , John Wiley & Sons, New York, 1995, pp. 192–194. 8. (a) Eigen, M. Pure Appl. Chem. 1963, 6, 105. (b) Bennetto, H. ; Caldin, E. F. J. Chem. Soc. A, 1971, 2198. 9. Tobe, M. L. , Pergamon Press, Oxford, 1987, pp. 281–329. 10. Shriver, D. ; Atkins, P. ; Langford, C. H. Inorganic Chemistry, Oxford University Press, Oxford, 1990, pp. 477–478. 11. Waern, J. ; Harding, M. M. Inorg. , 2004, 43(1), 206–213. 12. (a) Waern, J. ; Harris, H. ; Harding, M. ; Dillon, C. T. J. Biol. Inorg. , 2005, 10(5), 443–452.

Another electron counting system classifies ligands according to an ionic contribution. Both these systems are more completely described in a website found at http://www. html. Many stable coordination complexes can be counted as having sixteen electrons (16-e rule), especially those having square-planar geometry and those bonded to aromatic rings through their π electronic systems. Some of these complexes, belonging to a group of compounds called metallocenes, bind to DNA and have antitumor properties.

Some of these will be the bioinorganic chemistry topics treated in Chapters 5, 6, and 7 of this text. The recently coined term, proteomics, refers to the study of a large collection of proteins that occur and function together in a particular biochemical entity such as a cell or other organelle. Important interactions among proteins in a proteome distinguish the proteome’s behavior as being more complex than that of a single protein studied individually. A second major area of biochemical importance concerns study of nucleotide polymerization to produce ribonucleic acids (RNA) and deoxyribonucleic acids (DNA).

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